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<meta content="Canty, A.J." name="eprints.creators_name" />
<meta content="Deacon, G.B." name="eprints.creators_name" />
<meta content="allan.canty@utas.edu.au" name="eprints.creators_id" />
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<meta content="The complexes, C6F5HgXL, [X = Br or C1; L, = 2,2'-bipyridyl (bipy), 1,lO-phenanthroline (phen), 3,4,7,8-tetramethyl-1,lO-phenanthroline(tmp), or 2,9-
dimethyl-1,lO-phenanthroline(dmp)], C6Cl5HgClL, (L, = phen, tmp, or dmp), and PhHgClL, (L, = phen or tmp), have been prepared, but attempts to prepare PhHgClbipy or complexes of phenylmercuric bromide were unsuccessful. Evidence that the complexes contain four-coordinate mercury has been obtained from infrared spectroscopy. A11 complexes, except C6Cl5HgClphen, C6Cl5HgC1dmp, and
PhHgCltmp, undergo complete or partial disproportionation reactions, 2RHgXL2 = L2HgX2 + R2HgL2 (or R2Hg + L2), in boiling benzene. Although disproportionation or low solubility precludes solution studies on the majority of the derivatives, it has been shown that C6F5HgXdmp complexes are monomeric in acetone and that PhHgClphen undergoes dissociation, PhHgClphen + PhHgCl + phen, in this
solvent." name="eprints.abstract" />
<meta content="1968" name="eprints.date" />
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<meta content="Australian Journal of Chemistry" name="eprints.publication" />
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<meta content="5" name="eprints.number" />
<meta content="1757-1767" name="eprints.pagerange" />
<meta content="10.1071/CH9681757" name="eprints.id_number" />
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<meta content="* Part VI, J. organomet. Chem., in press. Preliminary communications for Part VII: Canty,
A. J., Deacon, G. B., and Felder, P. W., Inorg. nzlcl. Chem. Lett., 1967,3,263; Deacon, G. B., and
Canty, A. J., Inorg. %ucl. Chem. Lett., 1968, 4, 128.
t Chemistry Department, Monash University, Clayton, Vie. 3168.
Evans, R. C., Mann, F. G., Peiser, H. S., and Purdie, D., J. chem. Soc., 1940, 1209.
Cass, R. C., Coates, G. E., and Hayter, R. G., J. chem. Soc., 1955, 4007.
Coates, G. E., and Ridley, D., J. chem. Soc., 1964, 166.
Coates, G. E. "Organometallic Compounds." 2nd. Edn, pp. 78-82. (Methuen: London
1960.)
Seyferth, D., and Towe, R. H., Inorg. Chem., 1962, 1, 185.
Coates, G. E., and Lauder, A., J. chem. Soc., 1965, 1857.
Brodersen, K., Chem. Ber., 1957, 90, 2703.
Schwarzenbach, G., and Schellenberg, &I., Helv. chim. Acta, 1965, 48, 28.
Goggin, P. L., and Woodward, L. A., Trans. Faraday Soc., 1962, 58, 1495.
Dessy, R. E., Budde, W. L., and Woodruff, C., J. Am. chem. Soc., 1962, 84, 1172.
* Pentachlorophenylmercuric chloride gives an adduct with 2,2'-bipyridyl of composition
(C,Cl,HgCl),bipy, the structure of which is still being investigated.12
l1 Sesmeyanov, A. S., Freidlina, R. Kh., and Borisov, A. E., Izv. Akad. Nauk S S S R , Otdel.
Khim. Nauk, 1945, 146 (Chem. Abstr., 1946, 40, 3451).
l2 Deacon, G. B., and Felder, P. TV., unpublished data.
Chambers, R. D., Coates, G. E., Livingstone, J. G., and Musgrave, W. K. R., J. chem. Soc.,
1962, 4367.
l4 Chambers, R. D., and Chivers, T., J. chem. Soc., 1964, 4782.
l6 Deacon, G. B., Green, J. H. S., and Kyholm, R. S., J. chem. Soc., 1965, 3411.
l6 Deacon, G. B., Green, J. H. S., and Kynaston, W., J. chem. Soc. (A), 1967, 158.
l7 Rausch, M. D., Tibbetts, F. E., and Gordon, H. B. J. organomet. Chem., 1966, 5, 493.
la Deacon, G. B., and Felder, P. W., Aust. J. Chem., 196'7, 20, 1587.
l9 Deacon, G. B., and Felder, P. W., J. chem. Soc. (C), 1967, 2313.
20 Deacon, G. B., J. organomet. Chem., in press.
21 Brown, D. H., Mohammed, A, and Sharp, D. W. A., Spectrochim. Acta, 1965, 21, 659.
22 Harrah, L. A., Ryan, 11. T., and Tamborski, C., Spectrochim. Acta, 1962, 18, 21.
23 Deacon, G. B., Jones, R. A., and Rogasoh, P. E., Aust. J. Chem., 1963, 16, 360.
24 BfcWhinnie, W. R., and Poller, R. C., Spectrochim. Acta, 1966, 22, 501.
26 IllcWhinnie, W. R., J. inorg. nucl. Chenz., 1964, 26, 15, 21.
Schilt, A. A,, and Taylor, R. C., J. inorg. nucl. Chern., 1959, 9, 211.
27 Konig, E., and Madeja, K., Spectrochirn. Acta, 1967, 23A, 45.
28 Delwaulle, M. L., Bull. Soc. chim. Fr., 1955, 1294.
29 Adams, D. If., Chatt, J., Davidson, J. M., and Gerratt, J., J. chem. Soc., 1963, 2189.
30 Deacon, G. B., Green, J. H. S., and Kynaston, W., Aust. J. Chem., 1966, 19, 1603.
31 Deacon, G. B., and Green, J. H. S., Chem. Commun., 1966, 629.
32 Clark, R. J. H., Spectrochim. Acta, 1965, 21, 955.
33 Chambers, R. D., and Chivers, T., Organomet. Chem. Rev., 1966, 1, 279.
34 Grdenic, D., Q. Rev. chem. Soc., 1965, 19, 303.
85 Lile, W. J., and Menzies, R. C., J. chem. Soc., 1950, 617.
88 Deacon, G. B., and Felder, P. W., Aust. J. Chem., 1966, 19, 2381.
3' Huheey, J. E., J. phys. Chem., 1966, 70, 2086.
Sill&, L. G., and Martell, A. E., (Eds.), "Stability Constants." Chem. Soc. Spec. Publ.
No. 17. (Chemical Society: London 1964.)
50 Jensen, F. R., Rickborn, B., and ;Miller, J. J., J. Am. chem. Soc., 1966, 88, 340.
40 Deacon, G. B., Aust. J. Chem., 1967, 20, 459.
41 Rao, K. K., Humphreys, C. J., and Rank, D. H., "Wavelength Standards in the Infrared."
p. 144. (Academic Press: New York 1966.)
42 Grigg, E. C. M., Hall, J. R., and Plowman, R. A,, Aust. J. Chem., 1962, 15, 425.
48 Connett, J. E., Davies, A. G., Deacon, G. B., and Green, J. H. S., J.chem.Soc.( C),1 966,106" name="eprints.referencetext" />
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<meta content="The complexes, C6F5HgXL, [X = Br or C1; L, = 2,2'-bipyridyl (bipy), 1,lO-phenanthroline (phen), 3,4,7,8-tetramethyl-1,lO-phenanthroline(tmp), or 2,9-
dimethyl-1,lO-phenanthroline(dmp)], C6Cl5HgClL, (L, = phen, tmp, or dmp), and PhHgClL, (L, = phen or tmp), have been prepared, but attempts to prepare PhHgClbipy or complexes of phenylmercuric bromide were unsuccessful. Evidence that the complexes contain four-coordinate mercury has been obtained from infrared spectroscopy. A11 complexes, except C6Cl5HgClphen, C6Cl5HgC1dmp, and
PhHgCltmp, undergo complete or partial disproportionation reactions, 2RHgXL2 = L2HgX2 + R2HgL2 (or R2Hg + L2), in boiling benzene. Although disproportionation or low solubility precludes solution studies on the majority of the derivatives, it has been shown that C6F5HgXdmp complexes are monomeric in acetone and that PhHgClphen undergoes dissociation, PhHgClphen + PhHgCl + phen, in this
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<h1 class="ep_tm_pagetitle">Organomercury Compounds VII. Complexes of Arylmercuric Halides with Bidentate Ligands</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Deacon, G.B.</span> (1968) <xhtml:em>Organomercury Compounds VII. Complexes of Arylmercuric Halides with Bidentate Ligands.</xhtml:em> Australian Journal of Chemistry, 21 (5). pp. 1757-1767. ISSN 0004-9425</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2857/1/AJC1968%2C_1757.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2857/1/AJC1968%2C_1757.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />571Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="3811" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://www.publish.csiro.au/nid/51/paper/CH9681757.htm">http://www.publish.csiro.au/nid/51/paper/CH9681757.htm</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The complexes, C6F5HgXL, [X = Br or C1; L, = 2,2'-bipyridyl (bipy), 1,lO-phenanthroline (phen), 3,4,7,8-tetramethyl-1,lO-phenanthroline(tmp), or 2,9-
dimethyl-1,lO-phenanthroline(dmp)], C6Cl5HgClL, (L, = phen, tmp, or dmp), and PhHgClL, (L, = phen or tmp), have been prepared, but attempts to prepare PhHgClbipy or complexes of phenylmercuric bromide were unsuccessful. Evidence that the complexes contain four-coordinate mercury has been obtained from infrared spectroscopy. A11 complexes, except C6Cl5HgClphen, C6Cl5HgC1dmp, and
PhHgCltmp, undergo complete or partial disproportionation reactions, 2RHgXL2 = L2HgX2 + R2HgL2 (or R2Hg + L2), in boiling benzene. Although disproportionation or low solubility precludes solution studies on the majority of the derivatives, it has been shown that C6F5HgXdmp complexes are monomeric in acetone and that PhHgClphen undergoes dissociation, PhHgClphen + PhHgCl + phen, in this
solvent.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2857</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">15 Jan 2008 12:18</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">18 Jan 2008 13:35</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2857;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2857">item control page</a></p>
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